Tuesday, August 17, 2021

GATE Chemical Engineering Questions and Answers - Mass Transfer

The following figure depicts steady one-dimensional diffusion of water vapour from the surface of water taken in a conical flask at room temperature. Derive the governing equation for determining the concentration profile of water vapour in the gas medium. Neglect change of level of water due to condensation. The temperatures of the gas and the liquid media are identical and constant.

GATE 2007


GATE 2007

                                                                                                            GATE 2007

            Answer:          (A)

 

If TA and TB are the boiling points of pure A and B respectively and TAB is that of a non homogeneous immisible mixture of A and B, then

(A)             TAB<TA and TB

(B)              TAB>TA and TB

(C)              TA>TAB>TB

(D)             TB>TAB>TA

                                                                                                                  GATE 2007

Answer:    (A)

 

In a distillation operation, it is desired to have a very high purity bottom product. Initially, a kettle-type reboiler is used at the bottom of the column and the following analytical equation is used to obtain the equilibrium trays in the exhausting section of the column.

GATE 2007

Where xm is the composition of the liquid leaving tray m. Tray m is the last equilibrium tray obtained by a McCabe Thiele graph of the exhausting section. If the kettle-type reboiler is replaced by a thermo-syphon reboiler, the analytical equation, for the exhausting section will be

GATE 2007

                                                                                                            GATE 2007

                Answer:          (C)

 

A 50 cm × 50 cm × 1 cm flat wet sheet weighing 2 kg initially, was dried from both the sides under constant drying rate period. It look 1000 secs for the weight of the sheet to reduce to 1.75 kg. Another 1 m × 1 m × 1 cm flat sheet is to be dried from one side only. Under the same drying rate and other conditions, time required for drying (in secs) from initial weight of 4 kg to 3 kg is

(A)             1000

(B)              1500

(C)              2000

(D)             2500

                                                                                                            GATE 2007

Answer:          (C)

 

It is desired to reduce the concentration of pyridine in 500 kg of aqueous solution from 20 weight percent to 5 wt percent in a single batch extraction using chlorobenzene as solvent. Equilibrium compositions (end points of the tie line) in terms of weight percent of pyridine-water-chlorobenzene are (5, 95, 0) and (11, 0, 89). The amount of pure solvent required in kg for the operation is

(A)             607

(B)              639

(C)              931

(D)             1501

                                                                                                            GATE 2007

            Answer:          (B)

 

Benzene in an air-benzene mixture is to be reduced from 5.2 mol% in the feed to 0.5 mol% by contacting with wash oil in a multistage countercurrent gas absorber. The inlet flow rate of air-benzene mixture is 10 mol/s while benzene free wash oil comes in at 9.5 mol/s. If the equilibrium curve is given as Y* = X, where Y* and X are equilibrium mole ratios of benzene in air and benzene in oil, the number of equilibrium stages required to achieve the above separation is

GATE 2007


(A)             12

(B)              10

(C)              8

(D)             6

                                                                                                            GATE 2007

            Answer:          (B)

 

Given the following statements listed from P to T, select the correct combination of TRUE statements from the choices that follow this list.

(P)       Plate columns are preferred when the operation involves liquids containing suspended solids.

(Q)       Packed towers are preferred if the liquids have a large foaming tendency.

(R)       The pressure drop through packed towers is more than the pressure drop through plate columns designed for the same duty

(S)       Packed columns are preferred when large temperature changes are involved in distillation operations.

(T)       Packed towers are cheaper than plate towers if highly corrosive fluids must be handled.

(A)             T, S, P

(B)              P, Q, T

(C)              S, R, T

(D)             R, Q, S

                                                                                                            GATE 2007

Answer:          (B)

 

If the percentage humidity of air (30°C, total pressure 100 kPa) is 24% and the saturation pressure of water vapour at that temperature is 4 kPa, the percent relative humidity and the absolute humidity of air are

(A)             25.2, 0.0062

(B)              25, 0.0035

(C)              20.7, 0.0055

(D)             18.2, 0.0035

                                                                                                                        GATE 2007

            Answer:          (A)

 

Common data for the next three questions

A binary distillation column separates 100 mol/h of a feed mixture into distillate D and residue W. The McCabe-Thiele diagram for this process is given below. The relative volatility for the binary system is constant at 2.4

GATE 2006

The distillate and residue flow rates (in mol/h) are

(A)             D = 48.4, W = 51.6

(B)              D = 51.6, W = 48.4

(C)              D = 54.7, W = 45.3

(D)             D = 45.3, W = 54.7

                                                                                                            GATE 2006

            Answer:          (A)

 

The ratio of liquid to vapour molar flow rates in the rectifying section is

(A)             0.64

(B)              1.00

(C)              1.55

(D)             1.80

                                                                                                            GATE 2006

            Answer:          (A)

 

The minimum number of theoretical stages (inclusive of reboiler) for this process is

(A)             5.2

(B)              6.1

(C)              7.8

(D)             Infinite

                                                                                                            GATE 2006

            Answer:          (C)

 

A saturated vapour is fed to a distillation column at 180 kmol/h. Both the rectifying and stripping section of the column operate at 60% of their respective flooding velocities. The flooding velocity of the rectifying section is twice that of the stripping section. The assumptions of constant molar overflow and constant molar vapour density throughout the column are valid. If the boil-up rate is 60 kmol/h, then the relationship between the diameters of the rectifying section (dr) and the stripping section (ds) is

GATE 2006

                                                                                                            GATE 2006

                Answer:          (A)

 

Experiments conducted with a sparingly dissolving cylinder wall in a flowing liquid yielded the following correlation for the Sherwood number

Sh = 0.023(Re)0.83(Sc)1/3

Assuming the applicability of the Chilton-Colburn analogy, the corresponding correlation for heat transfer is

(A)             St = 0.023(Gr)0.83(Pr)1/3

(B)              Sh = 0.023(Re)0.83(Pr)1/3

(C)              Jh = 0.023(Re)0.83(Pr)2/3

(D)             Nu = 0.069(We)0.5(Pr)4/3

                                                                                                      GATE 2006

Answer:    (B)

 

A drug tablet of mass M0 administered orally at time t = 0 reaches the intestine at time t = τ without losing any mass. From the intestine, the drug is absorbed into blood. The rate of absorption is found to be proportional to the mass of the drug in the intestine with the proportional constant k. Assuming no drug is lost from the blood, the total mass of the drug in the blood Mb at time t ≥ τ is given by

(A)             Mb = M0[1-exp{-k(t-τ)}]

(B)              Mb = M0[1-exp{-kτ)}]

(C)              Mb = M0[exp{-k(t-τ)}]

(D)             Mb = M0[1-exp{-k(t+τ)}]

                                                                                                                        GATE 2006

            Answer:          (C)

 

100 mol of a binary mixture F containing 60 mol% A (more volatile) and 40% B is treated in a batch distillation still. After 1 h, 70 mol of the distillate are collected leaving behind the residue W. Relative volatility α is 2. The governing equation is

Log(FxF/WxW) = α log[{F(1-xF)}/{W(1-xW)}]

The average mole fraction of A in the distillate is

(A)             0.43

(B)              0.61

(C)              0.69

(D)             0.73

                                                                                                                            GATE 2006

            Answer:          (C)

 

In a multistage counter current isothermal stripping column, the feed containing 0.05 mol of solute/mol solute free oil is treated with steam. The absorption factor A = 0.65. The equilibrium relation is given by Y* = 2X, where Y* and X refer to the equilibrium mole ratio in the steam and oil phases respectively. The Kremsen equation is given as follows (‘0’ refers liquid inlet at the top, NP refers to the last stage at the bottom).

GATE 2006

If the steam is initially free of solute and its exit molar ratio (mol solute/mol steam) is 0.0624, then the number of equilibrium stages required is

(A)             4.2

(B)              5.2

(C)              7.2

(D)             8.2

                                                                                                            GATE 2006

            Answer:          (B)


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